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Separation/Analysis of Congo Red by Using Poly (Ionic Liquid) Immobilized Magnetic Nanoparticles Magnetic Solid Phase Extraction Coupled with Fluorescence Spectrophotometry

Received: 15 November 2017     Accepted: 25 November 2017     Published: 2 January 2018
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Abstract

Magnetic solid phase extraction (MSPE) accompanied with fluorescence spectrophotometry using Poly (ionic liquid) immobilized magnetic nanoparticles (PIL-MNPs) as sorbent was introduced for Congo red analysis in food. Poly (1-vinyl-3-butylimidazolium) bromide immobilized (MNPs) were prepared through co-polymerization of 1-vinyl-3-hexylimidazolium-based ionic liquid and vinyl-modified magnetic particles. Some of different types of parameters, such as pH value, adsorption temperature and time, sample volume, eluent type, were studied. Under the optimum conditions, the preconcentration factor for AR was 27. The linear range, detection limit (DL), correlation coefficient (R) and relative standard deviation (RSD) were found to be 0.10-9.00μg/mL, 5.2μg/L, 0.9987 and 3.10% (n=3, c=4.00μg/mL). This method had been successfully applied to the separation / analysis of Congo red in real samples.

Published in Science Journal of Analytical Chemistry (Volume 5, Issue 6)
DOI 10.11648/j.sjac.20170506.17
Page(s) 113-118
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This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2018. Published by Science Publishing Group

Keywords

Congo Red, Poly (Ionic Liquid) Magnetic Nanoparticles, Magnetic Solid-Phase Extraction, Fluorescence Spectrophotometry

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Cite This Article
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    Almojtaba Abd Alkhalig Ahmed Bakheet, Xiashi Zhu. (2018). Separation/Analysis of Congo Red by Using Poly (Ionic Liquid) Immobilized Magnetic Nanoparticles Magnetic Solid Phase Extraction Coupled with Fluorescence Spectrophotometry. Science Journal of Analytical Chemistry, 5(6), 113-118. https://doi.org/10.11648/j.sjac.20170506.17

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    ACS Style

    Almojtaba Abd Alkhalig Ahmed Bakheet; Xiashi Zhu. Separation/Analysis of Congo Red by Using Poly (Ionic Liquid) Immobilized Magnetic Nanoparticles Magnetic Solid Phase Extraction Coupled with Fluorescence Spectrophotometry. Sci. J. Anal. Chem. 2018, 5(6), 113-118. doi: 10.11648/j.sjac.20170506.17

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    AMA Style

    Almojtaba Abd Alkhalig Ahmed Bakheet, Xiashi Zhu. Separation/Analysis of Congo Red by Using Poly (Ionic Liquid) Immobilized Magnetic Nanoparticles Magnetic Solid Phase Extraction Coupled with Fluorescence Spectrophotometry. Sci J Anal Chem. 2018;5(6):113-118. doi: 10.11648/j.sjac.20170506.17

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  • @article{10.11648/j.sjac.20170506.17,
      author = {Almojtaba Abd Alkhalig Ahmed Bakheet and Xiashi Zhu},
      title = {Separation/Analysis of Congo Red by Using Poly (Ionic Liquid) Immobilized Magnetic Nanoparticles Magnetic Solid Phase Extraction Coupled with Fluorescence Spectrophotometry},
      journal = {Science Journal of Analytical Chemistry},
      volume = {5},
      number = {6},
      pages = {113-118},
      doi = {10.11648/j.sjac.20170506.17},
      url = {https://doi.org/10.11648/j.sjac.20170506.17},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjac.20170506.17},
      abstract = {Magnetic solid phase extraction (MSPE) accompanied with fluorescence spectrophotometry using Poly (ionic liquid) immobilized magnetic nanoparticles (PIL-MNPs) as sorbent was introduced for Congo red analysis in food. Poly (1-vinyl-3-butylimidazolium) bromide immobilized (MNPs) were prepared through co-polymerization of 1-vinyl-3-hexylimidazolium-based ionic liquid and vinyl-modified magnetic particles. Some of different types of parameters, such as pH value, adsorption temperature and time, sample volume, eluent type, were studied. Under the optimum conditions, the preconcentration factor for AR was 27. The linear range, detection limit (DL), correlation coefficient (R) and relative standard deviation (RSD) were found to be 0.10-9.00μg/mL, 5.2μg/L, 0.9987 and 3.10% (n=3, c=4.00μg/mL). This method had been successfully applied to the separation / analysis of Congo red in real samples.},
     year = {2018}
    }
    

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  • TY  - JOUR
    T1  - Separation/Analysis of Congo Red by Using Poly (Ionic Liquid) Immobilized Magnetic Nanoparticles Magnetic Solid Phase Extraction Coupled with Fluorescence Spectrophotometry
    AU  - Almojtaba Abd Alkhalig Ahmed Bakheet
    AU  - Xiashi Zhu
    Y1  - 2018/01/02
    PY  - 2018
    N1  - https://doi.org/10.11648/j.sjac.20170506.17
    DO  - 10.11648/j.sjac.20170506.17
    T2  - Science Journal of Analytical Chemistry
    JF  - Science Journal of Analytical Chemistry
    JO  - Science Journal of Analytical Chemistry
    SP  - 113
    EP  - 118
    PB  - Science Publishing Group
    SN  - 2376-8053
    UR  - https://doi.org/10.11648/j.sjac.20170506.17
    AB  - Magnetic solid phase extraction (MSPE) accompanied with fluorescence spectrophotometry using Poly (ionic liquid) immobilized magnetic nanoparticles (PIL-MNPs) as sorbent was introduced for Congo red analysis in food. Poly (1-vinyl-3-butylimidazolium) bromide immobilized (MNPs) were prepared through co-polymerization of 1-vinyl-3-hexylimidazolium-based ionic liquid and vinyl-modified magnetic particles. Some of different types of parameters, such as pH value, adsorption temperature and time, sample volume, eluent type, were studied. Under the optimum conditions, the preconcentration factor for AR was 27. The linear range, detection limit (DL), correlation coefficient (R) and relative standard deviation (RSD) were found to be 0.10-9.00μg/mL, 5.2μg/L, 0.9987 and 3.10% (n=3, c=4.00μg/mL). This method had been successfully applied to the separation / analysis of Congo red in real samples.
    VL  - 5
    IS  - 6
    ER  - 

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Author Information
  • College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou, China

  • College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou, China

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